Buy custom Rate Coefficients for the OH + HC(O)C(O)H (Glyoxal) Reaction between 210 and 390 K
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| Topic: |
Science
|
| Number of pages / Number of words: |
28 / 7725 |
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A number
of the OH + aldehyde reactions exhibit non-Arrhenius behavior
and a negative temperature dependence, suggesting the formation
of a stable prereactive adduct.20 In addition, theoretical
studies, such as those for the reactions of formaldehyde, HC-
(O)H, and acetaldehyde, CH3C(O)H, with OH,21,22 have provided
evidence for an OH adduct as a reaction intermediate...
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Galano et al.23
have studied the reactions of OH with glyoxal and methylglyoxal,
CH3C(O)C(O)H, theoretically using ab initio quantum
chemical structure (BHandHLYP/6-311++G(d,p)) and energy
(CCSD(T)/6-311++G(d,p)) calculations combined with canonical
variational transition state theory. They report a reaction
* To whom correspondence should be addressed...
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Rate Coefficients for the OH + HC(O)C(O)H (Glyoxal) Reaction between 210 and 390 K
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