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Number of pages / Number of words: |
2 / 542 |
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One factor is that a fraction of TCE may have decomposed during distillation; another factor is that upon distillation, some of the mixture may have escaped the distilling flask due to foaming.
CONCLUSION:
This experiment proves that a cyclohexanone ? tetrachloroethane mixture does not obey Raoult's law for it is inseparable and reaches an azeotropic composition at 157...
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This point appears to be the maximum, thus one can deduce negative deviation from Raoult's law.
REFERENCES:
1. Shoemaker, D.P.; Garland, C.W.; Nibler J.W. In Experiments in Physical Chemistry. Binary Liquid-Vapor Phase Diagram. The McGraw-Hill Companies, INC. USA. 1996; 6th ed., p 207
2. John M. White, Physical Chemistry Laboratory Experiments, Prentice-Hall, Englewood Cliffs, NJ, 1975, Experiment 5...
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