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| Topic: |
Science
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| Number of pages / Number of words: |
4 / 1115 |
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This is because at infinite dilution, the distance between two neighbouring ions are large, so only the effect of the applied electric field is felt by the individual ions.
Kohlrausch found that the molar conductivity varies with the square root of the concentration for many solutions:
(5)
The limiting molar conductivity, ??m , is the molar conductivity at infinite dilution...
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It is constant and dependent on the electrolyte. On the other hand, the constant K is dependent on the stoichiometry of the electrolyte rather than on its nature. From a plot of ?m versus c1/2, ¬ the limiting molar conductivity can be obtained from extrapolation. These molar conductivities at infinite dilution can be used to determine conductivity at infinite dilution for individual ions to yield the law of the independent migration of ions...
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