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Benzene used to be extracted from coal gas, and is the basis for many chemicals used in medicine. It can now be man made through safer means, via the distillation of benzoic acid.
Diamonds can also be man made, but many jewellers and consumers prefer natural as opposed to "fake" diamonds. Also, as diamonds are incredibly hard, they have many uses in cutting machines and other applications...
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Also, as diamonds are incredibly hard, they have many uses in cutting machines and other applications. Therefore, demand for diamonds will remain high as there are few other things that can be used instead.
Plastic has also begun to substitute metals in many household appliances, but the computer industry in particular, along with construction and automobiles still require high volumes of metals, as other options (such as carbon fibre in cars) are too expensive to be used instead...
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