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They determine this by comparing mass chromatograms of known drugs with that of the test sample. The gas chromatograph/mass spectrometer is known as the best resource to prove the identification of a chemical substance, such as a drug, because of the mass chromatographs that act like a fingerprint of a chemical substance...
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The instrumentation of the gas chromatograph/mass spectrometer is very complex. The instrument's parts include an injector, a carrier gas, a column, a separator, an ionization source, mass separator, and an ion detector. The injector is located on the gas chromatograph and is where the sample gas is injected into the instrument to start the process...
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